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Premier Wood Protectant Fungicide 5 Gallon Pail Concentrate

Premier Wood Protectant Fungicide 5 Gallon Pail Concentrate

Your Price: $295.00
Part Number:736

Our latest innovation in sapstain and mold control for fresh-cut lumber and wood products.

Premier® is an effective, water-emulsifiable formulation designed for long-lasting, broad-spectrum control of mold and stain fungi. In fact, our formulation has been evaluated with outstanding results by independent testing laboratories, sawmills and test sites. For effective sapstain control, Premier can be applied by spraying or dipping fresh-cut lumber. It’s ideal for treating softwoods including Douglas and white fir, spruce, hemlock and pine, as well as hardwoods such as oak, poplar and maple. Plus it’s easy to handle, user friendly and has a pleasant citrus odor. For insect control, it's compatible with commonly used water-dilutable insecticides such as X-Lance®.

Quick Facts

  • Long-lasting stain and mold control on freshly cut lumber, timbers and peeled logs.
  • Suitable for both softwoods and hardwoods.
  • No buffering is required.
  • Easy to handle and is user friendly.
  • Can be sprayed or dipped on freshly cut wood (treatment recommended within 24 hours).
  •     SAFETY DATA SHEET            ISK BIOCIDES, INC.
     
     
    SECTION 1:  Identification
     Product identifier:  Premier®. Other means of identification:  None. SDS number:  ISK015 Recommended use:  Sapstain & Mold Control for fresh cut lumber and wood products. Recommended restrictions:  None known. Manufacturer/Importer/Supplier/Distributor information: Company name:  ISK Biocides, Inc.  Address:  416 East Brooks Road,    Memphis.     TN 38109. Telephone:  Office hours (Mon – Fri)    7:00 – 4:30pm (Central time).   (901) 344-5350 or (800) 248-7961. Contact Person:  Anthony Accampo or Gail Watson E-mail:  SDSInquiry@iskbiocides.com Emergency phone number:  Chemtrec (800) 424-9300 (24 hours).
     
    SECTION 2:  Hazard(s) identification
     Classification of the chemical in accordance with paragraph (d) of §1910.1200:
     
    Physical hazards: None.
     Health hazards: Serious eye irritation Category 2A. Skin sensitization Category 1.
     
    Environmental hazards: Aquatic acute Category 1. Aquatic chronic Category 1.
     Signal word:   WARNING    Hazard statement(s): Causes serious eye irritation.  May cause an allergic skin reaction.  Very toxic to aquatic life.  Very toxic to aquatic life with long lasting effects.
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 2 of 13
    Hazard symbol(s): 
                                                                            Precautionary statement(s):   Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray.   Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace.   Avoid release to the environment. Wear eye protection/face protection. Wear protective gloves.      Response:  IF ON SKIN: Wash with plenty of soap and water.   IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.   Specific treatment (see instructions on this label).   If skin irritation or a rash occurs: Get medical advice/attention.   If eye irritation persists get medical advice/attention.   Wash contaminated clothing before reuse.   Collect spillage.    Storage: None.    Disposal: Dispose of contents/container to an appropriate treatment    and disposal facility in accordance with applicable laws    and regulations.
     Hazard(s) not otherwise  Classified (HNOC):  None known.
     Percentage of ingredient(s) of unknown acute toxicity: 
     32% of the mixture consists of ingredients of unknown acute toxicity (oral). 32% of the mixture consists of ingredients of unknown acute toxicity (dermal). 35% of the mixture consists of ingredients of unknown acute toxicity (inhalation).
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 3 of 13
    SECTION 3:  Composition/information on ingredients
     Mixture:
     Chemical name Concentration (weight %) CAS# D-Limonene Technical Grade 5% 94266-47-4 3-Iodo-2-propynyl butyl carbamate 4.5 – 7.5% 55406-53-6 Solvent naphtha, petroleum, light aromatic 1.5 – 4.5% 64742-95-6 1,2,4-Trimethylbenzene < 1.2% 95-63-6 Dimethyl sulfoxide 1.5 – 3% 67-68-5 Proprietary Component 0 – 10% Proprietary Propiconazole 3% 60207-90-1
     
    The specific chemical identity and/or exact percentage (concentrate) of composition has been withheld under trade secret rights.
     
     
    SECTION 4:  First-aid Measures
     Inhalation: If symptoms of overexposure are experienced, move person to fresh air.  If symptoms persist, call a poison control center or seek medical attention. 
     Skin contact: Skin contact may cause irritation or sensitization (allergic reaction). Take off contaminated clothing and  rinse skin for at least 15 – 20 minutes.  If irritation persists, call a poison control center or seek medical attention. 
     Eye contact: May cause irritation.  Irrigate eye with water for at least 15 – 20 minutes.  Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.  If irritation persists, call a poison control center or seek medical attention.
     Ingestion: Immediately call a poison control center or seek medical advice.  Do not induce vomiting unless told to do so by a poison control center or doctor.  Do not give any liquid to the person.  Do not give anything by mouth to an unconscious person.   Most important symptoms/effects, acute and delayed: May cause redness, swelling and tearing of the eyes. Swallowing large amounts may be harmful and may result in nausea, vomiting, diarrhea, and include central nervous system effects such as dizziness, drowsiness, weakness, fatigue, headache, and possible unconsciousness. May cause sensitization in humans.
     Indication of immediate medical attention and special treatment needed: If any symptoms described above are noted, contact a physician and give them this SDS sheet. 
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 4 of 13
     
     
    SECTION 5:  Fire-fighting measures
     Suitable extinguishing media: Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Use water spray to cool fire exposed containers. Water or foam may cause some foam and frothing. Unsuitable extinguishing media: None known.
     
     Specific hazards arising from the chemical: Thermal decomposition may produce toxic fumes  Hazardous combustion products may include: Carbon monoxide, Carbon dioxide, Nitrogen, Sulfur, and possibly Iodine, Formaldehyde and Methyl mercaptan.
     Special protective equipment and precautions for fire-fighters: Wear special chemical protective clothing and positive pressure self-contained breathing apparatus. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Decontaminate or discard any clothing that may contain chemical residue.
     
    SECTION 6: Accidental release measures
     Personal precautions, protective equipment and emergency procedures:  Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. 
     Methods and materials for containment and cleaning up:  SMALL SPILL: Wear appropriate personal protective equipment (see Section 8). Remove ignition sources and recover free liquid. Absorb remainder with sand or clay and place in a waste receptacle. Surfaces may be slippery.
     
    LARGE SPILL: Wear appropriate personal protective equipment (see Section 8). Restrict access to contaminated area. Remove ignition sources, stop spill at source. Dike to prevent spreading, and pump liquid to a recovery vessel. Absorb remainder of material with sand or clay and place in a properly labeled waste receptacle. Follow all local, state, and federal regulations for disposal. Do not contaminate water while cleaning equipment or disposing of wastes. Prohibit contamination of streams, lakes, or other bodies of water. 
     
    SECTION 7: Handling and Storage
     Precautions for safe handling: Observe good personal hygiene practices. Change protective gloves/clothing when signs of contamination appear. Keep out of reach of children. Avoid getting this material into contact with your skin and eyes.  Use this product with adequate ventilation.  Read and follow the directions on the product label; they are the best guide to using this product in the most effective way, and give the necessary safety precautions to protect your health.
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 5 of 13
    Conditions for safe storage, including any incompatibles: Do not store in metal containers.  Storing the concentrate in metal containers at elevated temperatures (>122ºF) will cause significant corrosion to mild steel within four months. Store in a secure, well-ventilated area protected from extreme temperatures. Do not transfer to an unmarked container. Keep container closed when not in use. (See Section 10 for incompatibles). . SECTION 8: Exposure controls/personal protection
     Control Parameters: Occupational exposure limits:
     US OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):  Permissible Exposure Limits Substance PEL-TWA  (8 hour) PEL-STEL  (15 min) D-Limonene Not available Not available 3-Iodo-2-propynyl butyl carbamate Not available Not available Solvent naphtha, petroleum, light aromatic Not available Not available 1,2,4-Trimethylbenzene Not available Not available Dimethyl sulfoxide Not available Not available Proprietary Component Not available Not available Propiconazole Not available Not available
     
     
    ACGIH Threshold Limit Values Substance TLV-TWA  (8 hour)
    TLV-STEL (15 min) D-Limonene  Not available Not available 3-Iodo-2-propynyl butyl carbamate Not available Not available Solvent naphtha, petroleum, light aromatic Not available Not available 1,2,4-Trimethylbenzene Not available Not available Dimethyl sulfoxide Not available Not available Proprietary Component Not available Not available Propiconazole Not available Not available
     
     
     
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 6 of 13
    Other Exposure Limits:  D-Limonene: 8hr TWA 30 ppm (AIHA Standard).      1,2,4-trimethylbenzene NIOSH TWA 25 ppm (125 mg/m3).   (US NIOSH Recommended Exposure Limits (RELs).
     
      Dimethyl Sulfoxide WEEL TWA 250 ppm.   (USA Workplace Environmental Exposure Levels (WEEL))
     Appropriate engineering controls: Ventilate via mechanical methods (general or local exhaust) to maintain exposure below TLV(s), if applicable. Good industrial hygiene practice dictates that indoor work areas should be isolated and provided with adequate local exhaust ventilation.
     Individual protection measures, such as personal protective equipment: Eye/face protection: If there is a potential for contact with the eyes, chemical worker's goggles or face shield should be used.
     
     Skin and Hand protection: Wear impervious gloves, such as Nitrile, and Neoprene to prevent repeated or prolonged skin contact. Special precautions should be taken to ensure that material cannot get inside gloves.
     Respiratory protection: Not normally needed in well-ventilated areas.  If TLV for product or any component is exceeded, use a MSHA/NIOSH-approved respirator.
     Other: Impervious boots (such as Nitrile, Neoprene), aprons, hats, or chemical suits  should be worn when necessary to prevent prolonged skin contact. Good personal hygiene practices should be used.  Wash after any contact, before eating and at the end of the work period.  Safety showers and eyewash stations should be provided in all areas in which this product is stored and/or handled.            Thermal hazards: None known. 
     
     
    SECTION 9: Physical and chemical properties
     Appearance:  Physical state:  Liquid.
      Form:  Clear translucent amber.   Color:  Translucent amber.  Odor:  Mild citrus. Odor threshold:  Not available.  pH: 6.0 – 7.0  Melting point/freezing point: Not known.  Initial Boiling point/Boiling Range: Not known. Flash point:  > 200oF PMCC. Evaporation rate: < 1 (nBuAC=1) Flammability (solid, gas):  Not available.
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 7 of 13
    Upper/lower flammability or explosive limits  Flammability limit – lower: Not determined.  Flammability limit – upper: Not determined.  Explosive limit – lower: Not determined.  Explosive limit – upper: Not determined. Vapor pressure: Unknown. Vapor density:  > 1 (air = 1). Relative density (Specific gravity):  1.01 Solubilities (water, other):  Soluble. Partition coefficient (n-octanol/water): Not available. Auto-ignition temperature: Not known. Decomposition temperature:  Not available. Viscosity:  275 - 350 cPs Brookfield #2 @ 20 rpm at 70oF. Other information:  Bulk density:  8.4 lbs per gal (weight per gallon cup).  VOC:  201 g/L – 1.67 lbs/gal – 19.1 weight %
     
    SECTION 10: Stability and Reactivity 
     Reactivity: Stable.  Chemical stability: This material is stable under normal handling and storage conditions.    Possibility of hazardous reactions: Thermal decomposition may produce toxic fumes.  Material is not known to polymerize. Conditions to avoid: None known. Incompatible materials: None known. Hazardous decomposition Products: Carbon monoxide, Carbon dioxide, Nitrogen, Sulfur, and possibly Iodine, Formaldehyde and Methyl mercaptan.
     
    SECTION 11: Toxicological information 
     Information on likely routes of exposure:  Inhalation: May cause irritation to nose, throat, respiratory tract, and may cause  central nervous system effects, such as dizziness, drowsiness, weakness, fatigue,  headache, and possible unconsciousness.
     Ingestion: Swallowing large amounts may be harmful and may result in nausea, vomiting, diarrhea, and include central nervous system effects as described under inhalation hazards.
     Skin: Slight to mild irritation. May cause erythema (redness), edema (swelling), and cracking of skin on prolonged or repeated contact. May cause sensitization in  humans.
     Eye: No corneal or iridal effects. May cause redness, swelling and tearing of the eyes.
     
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 8 of 13
    Symptoms related to the physical, chemical, and toxicological characteristics: Persons with pre-existing respiratory, eye, or skin disorders, liver or kidney impairments, may be more susceptible.
     Delayed and immediate effects and chronic effects from short or long-term exposure: None known.
     Acute toxicity:  Ingredient Information:
     
    Substance Test Type (species) Value
    D-Limonene
    LD50 Oral (Rabbit) > 5000 mg/kg LD50 Dermal (Rabbit) > 5000 mg/kg RD50 Inhalation (Mouse) > 1000 mg/kg
    3-Iodo-2-propynyl butyl carbamate
    LD50 Oral (Rat) Not available LD50 Dermal (Rabbit) Not available LC50 Inhalation, (Rat) Not available
    Solvent naphtha, petroleum, light aromatic
    LD50 Oral (Rat) >14000 mg/kg LD50 Dermal (Rabbit) >2000 mg/kg LC50 Inhalation, (Rat) 6000 - 10000 mg/m3 (4h)
    1,2,4Trimethylbenzene
    LD50 Oral (Rat) 5,000 mg/kg LD50 Dermal (Rabbit) 18,000 mg/m3 (4h) LC50 Inhalation, (Rat) Not available
    Dimethyl sulfoxide
    LD50 Oral (Rat) 14500 mg/kg LD50 Dermal (Rabbit) > 5000 mg/kg LC50 Inhalation, (Rat) 40250 ppm  (4h)
    Proprietary Component
    LD50 Oral (Rat) Not available LD50 Dermal (Rabbit) Not available LC50 Inhalation, (Rat) Not available
    Propiconazole
    LD50 Oral (Rat)  1517 mg/kg LD50 Dermal (Rabbit)  > 4000 mg/kg LC50 Inhalation (Rat)   1264 mg/m3 (4h)
     
    Product Acute Toxicity Estimates: Oral: Rat - LD50 - > 5000 mg/kg. Dermal: Rat - LD50 - > 5000 mg/kg. Inhalation (4h): Rat - LC50 – > 2.4 mg/l.
     Skin corrosion/irritation: Primary Skin Irritation (Rabbits): Slight to mild irritation.
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 9 of 13
     
    Serious eye damage/eye irritation: Primary Eye Irritation (rabbit): No corneal or iridal effects.
     Respiratory sensitization: Based upon information available on the known components, the product is not anticipated to cause respiratory sensitization.
     Skin sensitization: Dermal Sensitizer (guinea pig): Sensitizer.
     Germ cell mutagenicity: Based upon information available on the known components, the product is not anticipated to cause germ cell mutagenicity.
     Carcinogenicity: Based upon information available on the known components, the product is not anticipated to be a carcinogen.
     Reproductive toxicity: Based upon information available on the known components, the product is not anticipated to have reproductive toxicity. Specific target organ toxicity-  Single exposure: Based upon information available on the known components, the product is not anticipated to cause specific target organ toxicity to the respiratory system after a single exposure.
     Specific target organ toxicity- Repeat exposure: Based upon information available on the known components, the product is not anticipated to cause specific target organ toxicity after repeated or prolonged exposure.
     Aspiration hazard: Based upon information available on the known components, is not expected to be an aspiration hazard.
     Further information: Not available.
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 10 of 13
    SECTION 12: Ecological information 
     Ecotoxicity Product data: No data available.
     Ingredient Information:
     
    Substance Test Type Species Value
    D-Limonene
    LC50  Fish No data available EC50    Invertebrate No data available LC50   Algae No data available
    3-Iodo-2-propynyl butyl carbamate
     
    LC50 Oncorhynchus mykiss (rainbow trout)
    Fish 0.067 mg/l  - 96h
    EC50  Daphnia magna (Water flea) Invertebrate 0.04 mg/l  - 48h LC50   Algae No data available
    Solvent naphtha, petroleum, light aromatic
    LC50 Oncorhynchus mykiss (rainbow trout)
    Fish 9.2 mg/l – 96h
    EC50  Daphnia magna (Water flea) Invertebrate 100 mg/l – 48h LC50   Algae No data available
    1,2,4trimethylbenzene
    LC50 Pimephales promelas (fathead minnow)
    Fish 7.72 mg/l  - 96h
    EC50  Daphnia magna (Water flea) Invertebrate 3.6 mg/l  - 48h LC50   Algae No data available
    Dimethyl sulfoxide
    LC50 Pimephales promelas (fathead minnow)
    Fish 34000 mg/l  - 96 h
    EC50  Daphnia pulex (Water flea) Invertebrate 27500 mg/l LC50   Algae No data available
    Proprietary Component
    LC50 Pimephales promelas (fathead minnow)
    Fish 34000 mg/l  - 96 h
    EC50  Daphnia pulex (Water flea) Invertebrate 27500 mg/l LC50   Algae No data available
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 11 of 13
    Propiconazole
    LC50 Oncorhynchus mykiss (rainbow trout)
    Fish 0.9 - 1.2 mg/l  - 96 h
    EC50 Daphnia magna (Water flea)    Invertebrate 4.8 mg/l  - 48 h LC50  Pseudokirchneriella subcapitata (green algae) Algae 5 mg/l  - 72 h
     
    Persistence and degradability: Not available.  Bioaccumulative potential: Not available. Mobility in soil: Not available.  Mobility in general: Not available. Other adverse effects: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
     
    SECTION 13: Disposal considerations
     Disposal instructions:   If these wastes cannot be disposed of according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. Open dumping is prohibited. Pesticide wastes are   acutely hazardous. Do not reuse empty container. Triple rinse container (or equivalent). Then    offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by    other procedures approved by state and local authorities.
     
    SECTION 14: Transport Information
     DOT: Not regulated.  IATA: Not regulated.  IMDG: Not regulated.
     Special precautions during transport: Not available.
     Bill of lading classification = Preservatives, wood, n.o.i NMFC 161490, sub 2.
     
    SECTION  15: Regulatory Information 
     USA:  FIFRA: Pesticide Registration:
     This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law.  These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals.
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 12 of 13
    Following is the hazard information as required on the pesticide label: 
     
    CAUTION Causes moderate eye irritation.  Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. This pesticide is toxic to fish and shrimp.
     United States Federal Regulations: SDS complies with the OSHA, 29 CFR 1910.1200.
     SARA Superfund and Reauthorization Act of 1986 Title III sections 302, 311,312 and 313: Section 302 – None of the chemicals are EPCRA hazards. 
     CERCLA/Superfund, 40 CFR 117, 302: Not listed. 
     
    CHEMICAL C.A.S. Number Weight % Section 311/312 D-Limonene 94266-47-4 5% Fire Hazard, Acute Health Hazard 3-Iodo-2-propynyl butyl carbamate 55406-53-6 4.5 – 7.5% Not listed Solvent naphtha, petroleum, light aromatic 64742-95-6 1.5 – 4.5% Fire Hazard, Acute Health Hazard 1,2,4Trimethylbenzene 95-63-6 < 1.2% Fire Hazard Dimethyl sulfoxide 67-68-5 1.5 – 3% Fire Hazard, Chronic Health Hazard Proprietary Component Proprietary 0 – 10% Acute Health Hazard Propiconazole 60207-90-1 3% Acute Health Hazard
     
    Section 313 – List of Toxic Chemicals (40CFC 372): This product contains the following components (at level of 1% or greater) found on the 313 list of Toxic Chemicals. 3-Iodo-2propynyl butylcarbamate, 1,2,4-Trimethylbenzene, Propiconazole.
     Toxic Substance Control Act (TSCA): All substances are TSCA listed.
     Federal Water Pollution Control Act, Clean Water Act, 40 CFR 401.15 (formerly section 307) 40 CFR 116 (formerly section 311): This product does not contain listed chemicals. 
     
    Premier SDS#: ISK015.
     
    Revision Date: February 2, 2016 Page 13 of 13
    STATE REGULATIONS:
     This SDS contains specific health and safety data is applicable for state requirements. For details on your regulatory requirements you should contact the appropriate agency in your state.
     California Proposition 65:  This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
     New Jersey Right to Know: The following components are listed on the New Jersey Right to Know list: 3-Iodo-2-propynyl butylcarbamate, 1,2,4-Trimethylbenzene, Dimethyl sulfoxide, Propiconazole.
     Pennsylvania Right to Know: The following components are listed on the Pennsylvania Right to Know list: 3-Iodo-2-propynyl butylcarbamate, 1,2,4-Trimethylbenzene, Dimethyl sulfoxide,  Propiconazole.
     Massachusetts Right to Know: The following components are listed on the Massachusetts Right to Know list: 1,2,4-Trimethylbenzene.
     INTERNATIONAL REGULATIONS:
     Canadian Regulations  Class D2B: Toxic material at  = 1% 
     Canadian Controlled Products Regulations (WHMIS): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.
     
    SECTION  16: Other Information 
     
    Revision Date: September 9, 2014.
     
    The information in this Safety Data Sheet is provided in good faith and is correct to the best of our knowledge, information and belief at the date of its publication.   The information given is designed only as guidance and is not to be considered a warranty or quality specification.  User is responsible to evaluate all available information when using product for any particular use, including, if necessary, conducting any tests needed to determine the suitability of the product for a particular use.  User is also responsible for compliance with all Federal, State, Provincial and Local laws and regulations.  ISK Biocides, Inc. assumes no responsibility for injury, damage or loss resulting from the use of the material.  NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE, INCLUDING THAT THE INFORMATION OR PRODUCT MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS, ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS

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